
School of Mechanical Engineering Seminar
January, May 5, 2014 at 15:00
Wolfson Building of Mechanical Engineering, Room 206
Solar electricity with photon-enhanced thermionic emission (PETE)
Prof. Abraham Kribus
School of Mechanical Engineering, Faculty of Engineering
Tel Aviv University, Israel
The efficiencies of photovoltaic and thermal conversion of solar energy are both limited by thermodynamics, and by the complexity required in real conversion devices. A novel third alternative of photon-enhanced thermionic emission (PETE) offers an intriguing synergy of direct photonic conversion together with thermal conversion, and theoretically may reach efficiency exceeding 70%. However, realizing this conversion path requires a major multi-disciplinary effort in semiconductor physics, surface science, thermal science, and systems engineering.
A PETE converter consists of a semiconductor cathode with a bandgap that is matched to the solar spectrum, and an anode separated by a vacuum gap. Illuminating the cathode with concentrated solar radiation increases the conduction band electron population and reduces the energy barrier to electron emission by two mechanisms: increasing temperature due to heating by thermalization, and photo-generation that increases the electron concentration above its equilibrium level. Coating the cathode with a material that lowers the electron affinity can further reduce the barrier to emission. Hence, PETE devices utilize both photonic and thermal processes for energy conversion. The anode receives electrons from the cathode, and is heated by thermalization of these electrons. This waste heat is removed from the anode by an external heat exchanger. It is possible to use this heat to drive a secondary thermal cycle (e.g., heat engine or thermoelectric converter) to generate additional electricity and increase the overall device efficiency. A theoretical analysis of the ideal performance limits shows that under 1,000 suns, efficiency of the two-stage PETE and thermal conversion can exceed 70%, higher than ideal PV cells and higher than ideal thermal conversion. Practical implementation, however, is not easy. Several major challenges related to materials and device engineering will be discussed. Much further research, as well as engineering ingenuity, are needed to resolve both the materials issues and the device level design challenges, on the path to realize the promise of PETE conversion.